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Synthesis of 2-acetamido-2-deoxy-3-O-β-d-galactopyrano-syl-d-galactose by the sequential use of β-d-galactosidases from bovine testes and escherichia coli

✍ Scribed by Lars Hedbys; Elisabet Johansson; Klaus Mosbach; Per-Olof Larsson; Alf Gunnarsson; Sigfrid Svensson


Book ID
107725809
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
484 KB
Volume
186
Category
Article
ISSN
0008-6215

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Synthesis of O-(2-acetamido-2-deoxy-β-d-
✍ Rexford L. Thomas; Rashmi Dubey; Saeed A. Abbas; Khushi L. Matta 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 934 KB

Condensation of 3-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D- glucopyranosyl)-2,4,6-tri-O-acetyl-alpha-D-galactopyranosyl bromide (1) with benzyl 2-acetamido-3,6-di-O-benzyl-2-deoxy-alpha-D-glucopyranoside in boiling benzene and in the presence of mercuric cyanide afforded a trisaccharide that