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Synthesis of 2-(1-Nitroalkylidene)-cycloalkanones

✍ Scribed by Boëlle, Jérôme; Schneider, Raphaël; Gérardin, Philippe; Loubinoux, Bernard


Book ID
120522668
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
268 KB
Volume
23
Category
Article
ISSN
0039-7911

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One-pot stereocontrolled cycloalkanone s
✍ Philip C. Bulman Page; Stephen J. Shutlleworth; Mark B. Schilling; David J. Tapo 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 280 KB

Ldthium enolates of Zacyl-1,Sdithiane l-oxides, generated in one pot from 1.3-dithiane l-oxide, undergo highly diastereoselective alkylation upon treatment with alkyl iodide% similar In slfu treatment of these substrates with diiodoalkanes furnishes the corresponding medium-ring cycloalkanones with