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Synthesis of 1d-3-deoxy- and -2,3-dideoxyphosphatidylinositol

✍ Scribed by Alan P. Kozikowski; Lixin Qiao; Werner Tückmantel; Garth Powis

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
665 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

were synthesized using the regioisomeric mixture of viburnitol 1,2:4,5-and 1,2:5,6-diacetonides as starting material. Selective acidic hydrolysis and subsequent benzylation or deoxygenation afforded lla,b as important intermediates. Compound 3 and 18 were of interest as putative antimetabolites of phosphatidylinositol-3-phosphate and as inhibitors of cancer cell colony formation.

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