Synthesis of 1‐Aryl‐1,2,3,4,5,6‐hexahydrophosphinine 1‐Oxides
✍ Scribed by Keglevich, György; Sipos, Melinda; Lengyel, Dóra; Forintos, Henrietta; Körtvélyesi, Tamás; Imre, Tímea; Tőke, László
- Book ID
- 120879261
- Publisher
- Taylor and Francis Group
- Year
- 2004
- Tongue
- English
- Weight
- 152 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0039-7911
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
The title compounds (2 and 4) obtained by the diastereoselective hydrogenation of the corresponding 1,2,3,6-tetrahydrophosphinine oxides (1 and 3) were subjected to a detailed quantum chemical study. The possible chair conformers were calculated at the HF/6-31G \* level of theory, according to which
## Abstract The trimethylaluminum‐mediated Michael addition of ethyl phenyl‐H‐phosphinate to 1,2‐dihydrophosphinine oxides (**1A**) yielded 3‐(EtOPhP(O))‐1,2,3,6‐tetrahydrophosphinine oxides (**4**) in a selective manner, as a mixture of only two diastereomers. In the above type of reactions (e.g.,