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Synthesis of 1‐Aryl‐1,2,3,4,5,6‐hexahydrophosphinine 1‐Oxides

✍ Scribed by Keglevich, György; Sipos, Melinda; Lengyel, Dóra; Forintos, Henrietta; Körtvélyesi, Tamás; Imre, Tímea; Tőke, László


Book ID
120879261
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
152 KB
Volume
34
Category
Article
ISSN
0039-7911

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A theoretical study on the conformation
✍ Tamás Körtvélyesi; Melinda Sipos; György Keglevich 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 1 views

The title compounds (2 and 4) obtained by the diastereoselective hydrogenation of the corresponding 1,2,3,6-tetrahydrophosphinine oxides (1 and 3) were subjected to a detailed quantum chemical study. The possible chair conformers were calculated at the HF/6-31G \* level of theory, according to which

New P-ligands: 3-(ethyl-phenylphosphinat
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## Abstract The trimethylaluminum‐mediated Michael addition of ethyl phenyl‐H‐phosphinate to 1,2‐dihydrophosphinine oxides (**1A**) yielded 3‐(EtOPhP(O))‐1,2,3,6‐tetrahydrophosphinine oxides (**4**) in a selective manner, as a mixture of only two diastereomers. In the above type of reactions (e.g.,