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Synthesis of 1,8-bis(cyclam) and 1,8-bis(azacrown) substituted anthracenes by palladium-catalyzed arylation of cyclam

✍ Scribed by Irina P Beletskaya; Alexei D Averin; Alla G Bessmertnykh; Franck Denat; Roger Guilard

Book ID: 104232396
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 69 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02356-5

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✦ Synopsis

The Pd-catalyzed arylation of cyclam, cyclen, and azacrown ethers by aryl halides was studied. Cofacial biscyclam and bisazacrown were synthesized by direct bonding of the anthracenyl spacer to a nitrogen atom of macrocycles.

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