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Synthesis of 1,7-diamino-1,2,6,7-tetradeoxy-2,6-imino-D-glycero-D-ido-heptitol by intramolecular amination of aziridine ring

✍ Scribed by T.K. Chakraborty; S. Jayaprakash

Book ID: 104258371
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 223 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10356-2

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✦ Synopsis

A novel intramolecular 6-exo opening of a terminal Boc-protected aziridine ring by a strategically located amino group in the molecule enacted the crucial cyclisation to furnish the key intermediate 10 with requisite deoxyamino imino sugar framework leading to the stereoselective synthesis of 1,7-diamino-1,2,6,7-tetradeoxy-2,6-imino-D-glycero-D-ido-heptitol (5).

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