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Synthesis of 1,5,9-cyclododecatriene-x-14C6

✍ Scribed by Alexander B. Susán; William P. Duncan

Publisher
John Wiley and Sons
Year
1981
Tongue
French
Weight
300 KB
Volume
18
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

A small‐scale synthesis of 1,5,9‐cyclododecatriene‐x‐^14^C~6~ is described. 1,3‐Butadiene‐1,4‐^14^C~2~, specific activity of 1.15 mCi/mmole, was prepared via the thermal decomposition of tetramethylene‐1,4‐^14^C~2~‐bis‐(trimethylammonium hydroxide) and immediately converted to a mixture of stereoisomers of 1,5,9‐cyclododecatriene‐x‐^14^C~6~ using a Ziegler catalyst prepared in situ. The overall radiochemical yield was 15% (based on K^14^CN).

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