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Synthesis of 1,4,2-dioxazolidines by the reaction of keto aldehydes with N-phenylhydroxylamine. Intramolecular [3 + 2] cycloaddition between the nitrone and carbonyl moieties

โœ Scribed by Sugimoto, Toshiya; Nojima, Masatomo; Kusabayashi, Shigekazu


Book ID
120213739
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
301 KB
Volume
55
Category
Article
ISSN
0022-3263

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Synthesis of 3,4-dihydro-2h-thiopyrans b
โœ Hiroshi Maruoka; Kenji Yamagata; Motoyoshi Yamazaki ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 32 KB

## Abstract Sulfonium ylides **1aโ€h** reacted with sodium iodide to afford the corresponding thiopyrans **2aโ€h.** On the other hand, compounds **1aโ€d** were treated with thionyl chloride to give the ring opening products **3aโ€d.** The reaction of compounds **3aโ€d** with sodium iodide and triethylam