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Synthesis of 1,4-Dithiins from Pentathiepins.

โœ Scribed by Stanislav A. Amelichev; Lidia S. Konstantinova; Natalia V. Obruchnikova; Oleg A. Rakitin; Charles W. Rees

Publisher
John Wiley and Sons
Year
2007
Weight
38 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

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Optimized geometries and energies for 3,4-dihydro-1,2-dithiin ลฝ . ลฝ . ลฝ . ลฝ . 1 , 3,6-dihydro-1,2-dithiin 2 , 4H-1,3-dithiin 3 , and 2,3-dihydro-1,4-dithiin 4 were calculated using ab initio 6-31G U and MP2r6-31G U rr6-31G U methods. At the MP2r6-31G U rr6-31G U level, the half-chair conformer of 4