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Synthesis of 1,3,5-Tricarbonyl Derivatives by Condensation of 1,3-Bis(silyl enol ethers) with Acid Chlorides.

โœ Scribed by Thomas Rahn; Van T. H. Nguyen; T. H. Tam Dang; Zafar Ahmed; Karen Methling; Michael Lalk; Christine Fischer; Anke Spannenberg; Peter Langer


Publisher
John Wiley and Sons
Year
2007
Weight
36 KB
Volume
38
Category
Article
ISSN
0931-7597

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Abstract

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[3+3] Cyclizations of 1,3-Bis(silyl enol
โœ Peter Langer; Gopal Bose ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 136 KB ๐Ÿ‘ 1 views

Domino reactions facilitate the rapid assembly of complex products in a one-pot process. [1] Despite the simplicity of the idea, domino cyclizations of 1,3-dicarbonyl dianions [2] with dielectrophiles are relatively rare. [3] As a result of their high negative charge density, ambident dianions are v