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SYNTHESIS OF 1,2,3,9,10,10A-HEXAHYDRO-3-KETO-PHENANTHRENES FROM 3-ARYL-7-ACETOXYCOUMARINS

✍ Scribed by Walker, Gordon N.


Book ID
127046122
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
231 KB
Volume
79
Category
Article
ISSN
0002-7863

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(4aSR,10aRS)-1,2,3,4,4a,10a-Hexahydro-6,
✍ Xiong, Yi ;Sun, Cui-Rong ;Hu, Mao-Lin ;Liu, Miao-Chang πŸ“‚ Article πŸ“… 2005 πŸ› International Union of Crystallography 🌐 English βš– 154 KB

The title diterpene, C 19 H 24 O 4 , which was totally synthesized from geranic acid, has the tricyclic backbone of a podocarpic diterpene. The skeleton does not show a planar configuration, but is distinctly bent.