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Synthesis of 1,2:3,4-diepoxides by catalyzed rearrangement of 1,4-endoperoxides

✍ Scribed by Boyd, Jack D.; Foote, Christopher S.; Imagawa, David K.


Book ID
118043061
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
259 KB
Volume
102
Category
Article
ISSN
0002-7863

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CoTPP-catalyzed rearrangement of 1.4-end
✍ Metin Balci; Yaşar SΓΌtbeyaz πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 170 KB

Bicyclic endoperoxides with strained and perturbed diene moiety have been submitted to CoTPP-catalyzed rearrangement. Side reaction, like formation of epoxyenone, has been suppressed and yield of the formation of bisepoxides highly increased.