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Synthesis of 1,2-Diamino-1,2-dideoxy- m yo - inositol-Derived Ligands for the Investigation of Metal Complex Reactivity

✍ Scribed by Azev, Viatcheslav N.; d'Alarcao, Marc


Book ID
126931718
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
76 KB
Volume
69
Category
Article
ISSN
0022-3263

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## Abstract A new, convenient, and safe route to 1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol (taci) was investigated by hydrogenation of azo‐coupled derivatives of phloroglucinol. In the presence of acetic anhydride, the reduction of trisphenylazophloroglucinol (H~2~/Pd(5%) on C) resulted in the