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Synthesis of 1,1,4,4-Tetrabromo-2-butenes and Related Compounds via Desilylation—Bromination of Silylated 1,3-Butadiene Derivatives.

✍ Scribed by Zhenfeng Xi; Xiaohong Liu; Jianming Lu; Fengyu Bao; Hongtao Fan; Zhiping Li; Tamotsu Takahashi


Publisher
John Wiley and Sons
Year
2005
Weight
35 KB
Volume
36
Category
Article
ISSN
0931-7597

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✍ Annette D. Allen; Ruizhi Ji; Wing-Yan Lai; Jihai Ma; Thomas T. Tidwell 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 1008 KB

The bisketenes 2-phenyl and 2-methyl-3-(trimethylsilyl)-1,3-butadiene-l,4dione (8 and 10) are calculated on the basis o f additivity of substituent effects to be less stable than the 3-phenyl and 3-methyl-4-(trimethylsilyI)cyclobut-3-ene-l,2-diones (7 and 9) by 1.9 and 2.6 kcal/mol, respectively. In