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Synthesis of 1,1,1,7,7,7-hexafluoroheptane-2,4,6-trione, the simplest fluorinated 1,3,5-triketone

✍ Scribed by Dmitri V. Sevenard; Olesya Kazakova; Dmitri L. Chizhov; Gerd-Volker Röschenthaler


Book ID
108170437
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
142 KB
Volume
127
Category
Article
ISSN
0022-1139

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Synthesis of 1,1,1,7,7,7-Hexafluorohepta
✍ Dmitri V. Sevenard; Olesya Kazakova; Dmitri L. Chizhov; Gerd-Volker Roeschenthal 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views

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7,7-Dimethyl-2-phenyl-6,7-dihydro-1,2,4-
✍ Dolzhenko, Anton V. ;Tan, Geok Kheng ;Koh, Lip Lin ;Dolzhenko, Anna V. ;Chui, Wa 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 494 KB

The title compound, C 12 H 14 N 6 , was synthesized via cyclocondensation of 5-guanidino-3-phenyl-1,2,4-triazole with acetone. Only one tautomeric form with the NH H atom vicinal to the methyl groups was observed in the crystal structure. The triazine ring adopts a flattened half-boat conformation.