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Synthesis of 1,1-bishomoadamant-3-ene (tricyclo[5.3.1.13,9]dodec-3-ene)

✍ Scribed by Ward, Harry D.; Murray, Roger K.


Book ID
120050674
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
568 KB
Volume
55
Category
Article
ISSN
0022-3263

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Bicyclo[3.2.O]hept-l(7)-ene and compounds containing this highly strained system have remained fugutive,2 although related compounds have been prepared. 2-5 The apparent instability of this system presumably arises from the twist imposed upon the double bond by the trimethylene bridge. When both bri