๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Synthesis of [10,10,10-2H3]geranyl diphosphate

โœ Scribed by Shunsuke Izumi; Mie Aihara; Yoshikazu Hiraga; Toshifumi Hirata; Takayuki Suga


Publisher
John Wiley and Sons
Year
1991
Tongue
French
Weight
251 KB
Volume
29
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

โœฆ Synopsis


Abstract

[10,10,10โ€^2^H~3~]โ€3, 7โ€Dimethylโ€2(E), 6โ€octadienyl diphosphate ([10,10,10โ€^2^H~3~]geranyl diphosphate) was synthesized from 6โ€(benzyloxy)โ€4โ€methylโ€4(E)โ€hexenal by regioselective deuteration involving a modified Wittig reaction as the key step.


๐Ÿ“œ SIMILAR VOLUMES


Synthesis of d8-geranyl diphosphate
โœ Daniel J. Comeskey; Daryl D. Rowan; Adam J. Matich ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 122 KB

Multiply labelled d 8 -geranyl diphosphate (3-methyl-7-2 H 3 -methyl-[1,1,8,8,8]-2 H 5 -2E,6-octadienyl diphosphate) was synthesised from geraniol in 8 steps. Geraniol was converted to [1,1]-2 H 2 -geraniol by a three step oxidation-reduction sequence in 38% yield. Selective epoxidation of [1,1]-2 H

Preparation of (10R,s-[10-3H]juvenile ho
โœ Fred. C. Baker; David A. Schooley ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 417 KB ๐Ÿ‘ 1 views

Samples of racemic [10-3H] juvenile hormone 111 (methyl (2~,6~)-lO,ll-epoxy-3,7,11-trimethyl-2,6-dodecadienoate) and [lo-3 Hljuvenile hormone 0 (methyl (2E,6~,10~)-3,7-diethyl-l0,1l-epoxy-ll-methyl-2,6-tridecadienoate~were prepared by NaB H4 reduction of the corresponding 1 I-chloro-lo-oxo ("chlorok

Synthesis and reactions of 10,10-dimethy
โœ Thomas Kappe; Franz Frรผhwirth; Peter Roschger; Brigitte Jocham; Jenny Kremsner; ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 70 KB

## Abstract Cyclocondensation of 2,3,3โ€trimefhylโ€3__H__โ€indoles **2** with malonates **3** gives 8โ€hydroxyโ€10,10โ€dimefhylโ€10__H__โ€pyrido[1,2โ€__a__]indolโ€6โ€ones **4**, which were halogenated in position 7, 8 and 9 with sulfuryl chloride, bromine or phosphoroxychloride to give the corresponding haloโ€