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Synthesis of (1 R ,2 R ,3 R ,7 R ,7a R )-Hexahydro-3-(Hydroxymethyl)-1 H -pyrrolizine-1,2,7-triol: 7-Epiaustraline

✍ Scribed by Denmark, Scott E.; Herbert, B.


Book ID
126329333
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
88 KB
Volume
120
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Synthesis of (1R,2R
✍ S. E. DENMARK; B. HERBERT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 1 views

Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3-(hydroxymethyl)-1Hpyrrolizine-1,2,7-triol: 7-Epiaustraline. -Title compound (VI) is synthesized from known nitronate (I), prepared via [4 + 2] cycloaddition, in order to establish [4 + 2]/[3 + 2] cycloaddition chemistry as a general strategy for the synthe