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Synthesis of 1-molybda-2-phosphatriazoline and -aziridine derivatives via 1,3-dipolar cycloaddition of aryl azides to .sigma.3,.lambda.4-phosphanediyl complexes

โœ Scribed by Lang, Heinrich; Leise, Michael; Zsolnai, Laszlo


Book ID
127284112
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
621 KB
Volume
12
Category
Article
ISSN
0276-7333

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Triazolines. XXXIII. Nonregiospecific 1,
โœ Zhaiwei Lin; Pankaja K. Kadaba ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 530 KB

The 1,3-cycloaddition of aryl azides to the olefinic bonds of 4- and 2-vinylpyridines has been found to yield pyridyl substituted aziridines as the main reaction products with only smaller amounts of the normally expected 1-aryl-5-pyridyl-1,2,3-triazolines. Theoretical and experimental evidence are