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Synthesis of 1-fluoro-1,1,3,3-tetranitro-5-oxahexane, 3-trifluoromethoxy-2,2-dinitropropanol, and 3-fluoro-2,2-dinitropropanol

โœ Scribed by Peters, Howard M.; Simon, Robert L.; Ross, Leonard O.; Ross, Donald L.; Hill, Marion E.


Book ID
125942191
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
490 KB
Volume
20
Category
Article
ISSN
0021-9568

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Synthesis of 3-fluoro-2-methyl-1(2h)-iso
โœ D.A. Kendrick; M. Kolb ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 214 KB

The title compound 9 is prepared in five steps from o-carboxy-benzaldehyde. In the key reaction, the amide functionality in N-methyl 2-(2,2difluoroethenyl)-benzencarboxamide is silylated to afford the iminoester N-methyl 2-(2,2difluoroethenyl)benzenetrimethyl silyl iminoester which cyclizes spontan