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Synthesis of 1-azaazulene and benz[a]azulene by carbene rearrangement

✍ Scribed by Wentrup, Curt; Becker, Juergen


Book ID
125839503
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
242 KB
Volume
106
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


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A tropylium-substituted cyclopropane has been prepared which is rigidly held in the "bisected" conformation. Its electrophilic reactions are also investigated. Bond length asymmetry in cyclopropanes, as induced by aromatic substituents, has recently been an object of attention in our 1aboratories.l

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We also wish to celebrate, on this occasion, the '60th anniversary' of the work of Pfau and Plutfner on the correct structure of azulenes which appeared in this journal [la]. )) According to the CSD, only one X-ray crystal structure of a benzazulene, namely that of 10-(methylamino)benzlflazulene, h