Synthesis of 1-[4-(3-Chlorobenzoyl)phenyl]-2-phenylacetylene
✍ Scribed by Davis, Matthew; Groshens, Thomas
- Book ID
- 127001082
- Publisher
- Taylor and Francis Group
- Year
- 2011
- Tongue
- English
- Weight
- 178 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0030-4948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Single -crystal X-ray study T = 120 K Mean (C-C) = 0.004 A R factor = 0.057 wR factor = 0.120 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The phenyl and benzoyl groups in the title molecule, C~14~H~11~ClN~2~OS, are __cis__ and __trans__, respectively, with respect to the C=S bond. The molecular conformation is stabilized by an N—H...O hydrogen bond and the crystal packing is characterized by N—H...O and N—H...S hydrogen bonds.
In the title compound, C 14 H 10 Cl 2 N 2 OS, the geometric parameters do not show unusual features. The thiocarbonyl and carbonyl groups are almost coplanar with the chlorophenyl ring, as reflected by the torsion angles of 0.7 (3) and À5.8 (3) , respectively. The structure exhibits inter-and intram