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Synthesis, molecular structure, and reactivity of (alkylperoxo)copper(II) complex

✍ Scribed by Kitajima, Nobumasa; Katayama, Tsutomu; Fujisawa, Kiyoshi; Iwata, Yusaku; Morooka, Yoshihiko

Book ID
115442744
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
254 KB
Volume
115
Category
Article
ISSN
0002-7863

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A detailed in situ 13 C and 1 H NMR spectroscopic characterization of the following families of alkylperoxo complexes of titanium is presented: Ti( 2 -OOtBu) n (OiPr) 4-n , where n = 1-4; binuclear complexes [(iPrO) 3 Ti(-OiPr) 2 Ti(OiPr) 2 ( 2 -OOtBu)] and [( 2 -OOtBu)(iPrO) 2 Ti(-OiPr) 2 Ti(OiPr)