Synthesis, molecular, spectroscopic and catalytic characterization of ruthenium(II) complexes with pyridine-2-carboxylic acid derivatives ligands
✍ Scribed by J.G. Małecki; S. Krompiec; A. Maroń; M. Penkala
- Book ID
- 119351716
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 1007 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0277-5387
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Ruthenium complexes of some tridentate and bidentate benzimidazole-, benzothiazole-and pyridine-derived ligands have been prepared as their PF 6 salts, and their constitutions have been confirmed by elemental analysis, ~H-n.m.r. spectroscopy and electrochemistry. The complexes are redox-active, disp
w Ž . x X Reaction of RuCl p-cymene with the tridentate N-N -N ligands, 2,6-pyridyl-diimines, led to substitution of 2 2 p-cymene. The resulting complexes, believed to be coordinatively unsaturated, exhibit efficient activity for the epoxidation Ž . of cyclohexene in the presence of iodosobenzene P