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Synthesis, Light Harvesting, and Energy Transfer Properties of a Zinc Porphyrin Linked Poly(phenyleneethynylene)

✍ Scribed by Nielsen, Kim T.; Spanggaard, Holger; Krebs, Frederik C.


Book ID
120208592
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
208 KB
Volume
38
Category
Article
ISSN
0024-9297

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A series of ortho-, meta-and para-substituted zinc porphyrin-pheophorbide dyads were synthesized directly from methyl pheophorbide-a by trans-esterification of ~-keto methyl ester with hydroxymethyl substituted porphyrins. Quantitative energy transfer occurred from the excited zinc porphyrin to the