✦ LIBER ✦

Synthesis, IR/Raman, and quantum-chemical structural analysis of new octathiotetraphosphetane ammonium salts

✍ Scribed by Elena K. Badeeva; Elena V. Platova; Elvira S. Batyeva; Lidiya I. Kursheva; Elena E. Zvereva; Aleksander. E. Vandyukov; Sergey A. Katsyuba; Valeryi I. Kovalenko; Oleg G. Sinyashin

Book ID: 102233796
Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 285 KB
Volume: 22
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20651

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✦ Synopsis

Abstract

New octathiotetraphosphetane ammonium salts are obtained based on the reaction of white phosphorus (P~4~) and elemental sulfur with aliphatic mercaptans in the presence of amines (morpholine**,** methylmorpholine, pyrrolidine, and N,N‐dimethylbenzylamine). Both the salts and novel Cu(I) chloride complex with the pyperidinium salt of octathiotetraphosphetane are characterized by IR/Raman spectroscopy in combination with DFT methods. The comparative spectral analysis reveals clear spectral features, characteristic for a P~4~S~8~^4−^ anion, which are present in IR and Raman spectra of all the compounds obtained. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 22:24–30, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20651

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