Synthesis, Fluorescence Properties, and Head-to-Tail Regioselectivity in the Photodimerization of a Donor–Acceptor-Substituted Anthracene
✍ Scribed by Heiko Ihmels
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 278 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
The novel 2,6-donor-acceptor-substituted anthracene, of the anthracene 7 in solution yields the syn and anti headto-tail dimers exclusively. A synergistic electronic effect namely 6-methoxy-2-anthracene carboxylic acid ( ), was synthesized. The emission of this compound exhibits between the donor and acceptor substituents is proposed to operate on the photophysical and photochemical properties significant solvatochromism. The fluorescence band position and intensity are also remarkably sensitive to H + . Irradiation of anthracene 7.
the synthesis of the 2,6-donorϪacceptor-substituted 6-Alder reaction with fumaric acid to give the Am Hubland, D-97074