Synthesis, features and thermal decomposition of hexachlorostannates and hexachloroplatinates of tris(2,2′-dipyridyl)metal(II) and tris(1,10-phenanthroline)metal(II) (metal=Ru, Fe, Ni)
✍ Scribed by J. Lubkowski; A. Bujewski; J. Szychlinski; M. Walewski; J. Blazejowski
- Publisher
- Springer Netherlands
- Year
- 1992
- Tongue
- English
- Weight
- 285 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-5215
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📜 SIMILAR VOLUMES
C Chemical shifts are reported for the ruthenium(II) tris complexes of thirteen 2,Z-bipyridyls and three 1,lO-phenanthrolines and for the osmium(]") bris complexes of five 2,2'-bpyridyls. Chelation induced shifts -&3 are discussed in terms of models for n back-bonding. -C NMR is shown to be a conven
of the pH and of the concentrations of buffers and acetonitrile. With the trans-14-macrocycle IV the kinetics are completely described by a second order rate constant: - For the other ligands, the same rate law is obtained from initial rates. Stability constants and standard potentials of the CuL'