Synthesis, electrochemistry, reactivity, and structural studies of the early/late transition metal heterobimetallic complex [Cp2Ti(SCH2CH2PPh2)2Ni]

Early metal thiolato species as metallol

Early metal thiolato species as metalloligands in the formation of early/late heterobimetallic complexes: syntheses and molecular structures of Cp2Ti(SMe)2, Cp2V(SMe)2, (Cp2Ti(.mu.-SMe)2)2Ni and (Ni(.mu.-SMe)2)6

✍ Wark, Teresa A.; Stephan, Douglas W. 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 987 KB

Preparation, characterization, and react

Preparation, characterization, and reactivity of the early-transition-metal/late-transition-metal heterobimetallic complexes (C5H5)2Zr(.mu.-PPh2)2MLn (M = Ni, Pd, Pt)

✍ Gelmini, Lucio; Stephan, Douglas W. 📂 Article 📅 1986 🏛 American Chemical Society 🌐 English ⚖ 561 KB

Preparation, reactivity, hydroformylatio

Preparation, reactivity, hydroformylation catalysis, and structural studies of the early transition metal/late transition metal heterobimetallic complexes Cp2M(.mu.-PR2)2M'H(CO)PPh3 (M = Zr, Hf; M' = Rh, Ir)

✍ Gelmini, Lucio.; Stephan, Douglas W. 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 900 KB

Early metal thiolato species as metallol

Early metal thiolato species as metalloligands in the formation of early/late heterobimetallic complexes: syntheses and molecular structures of Cp2Ti(SMe)2, Cp2V(SMe)2, (Cp2Ti(.mu.-SMe)2)2Ni and (Ni(-SMe)2)6 [Erratum to document cited in CA111(25):233165h]

✍ Wark, Teresa A.; Stephan, Douglas W. 📂 Article 📅 1990 🏛 American Chemical Society 🌐 English ⚖ 34 KB

Synthesis, Structure, Electrochemistry a

Synthesis, Structure, Electrochemistry and Reactivity of the Bis(μ-σ-stannanediyl)dinickel Butterfly Cluster [{{(SiMe3)2CH}2Sn–Ni(η5-Cp)}2](Ni2–Sn2)

✍ Jörg J. Schneider; Jörg Hagen; Dieter Bläser; Roland Boese; Fabrizia Fabrizi de 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB 👁 1 views

Addition of stannylene [{(SiMe 3 ) 2 CH} 2 Sn:] (2) to the unbridged water results in the cleavage of an Ni-Sn bond and subsequent opening of the cluster cage of 3 to form the trinuclear homobimetallic Ni-Ni bond of [{PEt 3 Ni(η 5 -Cp)} 2 ] (1) gives the heterobimetallic, tetranuclear compound [{{(S

The reactivity of the metalmetal bond i

The reactivity of the metalmetal bond in the dimer [(CH3C(CH2PPh2)3)2Rh2(μ-CO)2]·(CH3)2CO. Synthesis and X-ray structure of a paramagnetic dinuclear rhodium complex

✍ Franco Cecconi; Carlo A. Ghilardi; Stefano Midollini; Annabella Orlandini; Piero 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 340 KB