The aldehydes 1 and 5 were converted to the corresponding SAMP hydrazones 2 and 6, respectively. Subsequent nucleophilic 1,2-addition of organolithium reagents to the CϪN double bonds and cleavage of the NϪN hydrazine bond using an excess of BH 3 • THF afforded (1-ferrocenylalkyl)ami-
Synthesis, electrochemical properties and fungicidal activity of 1,1′-bis(aroyl)ferrocenes and their derivatives
✍ Scribed by Yan-Ye Dou; Yun-Fu Xie; Liang-Fu Tang
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 155 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.1345
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## Abstract A convenient method for synthesis of novel 1‐[pyrimidinyl], 1‐[1,3,5‐triazin‐2‐carbonyl], and 1‐[thiazol‐5‐carbonyl] derivatives of 3‐thioxo‐diaziridine **1**, **3**, **5**, and **7** from corresponding hydrazides, CS2, and KOH is elaborated. The highest reaction yield was observed when
## Abstract magnified image A series of ethyl 2‐(1,5‐diaryl‐1__H__‐pyrazol‐3‐yloxy)acetate derivatives (**5a**, **5b**, **5c**, **5d**, **5e**, **5f**, **5g**, **5h**, **5i**) have been efficiently synthesized by the reaction of 1,5‐diaryl‐1__H__‐pyrazol‐3‐ols (**4a**, **4b**, **4c**, **4d**, **4e