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Synthesis, electrochemical, magnetic, catalytic and antimicrobial studies of N-functionalized cyclam based trinuclear copper(II) and nickel(II) complexes

✍ Scribed by S. Sreedaran; K. Shanmuga Bharathi; A. Kalilur Rahiman; L. Jagadish; V. Kaviyarasan; V. Narayanan


Publisher
Springer Netherlands
Year
2009
Tongue
English
Weight
433 KB
Volume
66
Category
Article
ISSN
0923-0750

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Trinuclear Triangular Copper(II) Cluster
✍ Corrado Di Nicola; Federica Garau; Yauhen Y. Karabach; LuΓ­sa M. D. R. S. Martins πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 441 KB

## Abstract The reactions of Cu^II^ carboxylates (valerate, 2‐methylbutyrate, hexanoate, heptanoate) with pyrazole (Hpz) in EtOH or EtOH/water solutions easily afford the triangular trinuclear copper derivatives [Cu~3~(ΞΌ~3~‐OH)(μ‐pz)~3~(RCOO)~2~(L)__~x~__] [R = CH~3~(CH~2~)~3~, L = H~2~O, __x__ = 1