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Synthesis, Electrochemical, and Photophysical Study of Covalently Linked Porphyrin Dimers with Two Different Macrocycles

โœ Scribed by Kadish, Karl M.; Guo, Ning; Caemelbecke, Eric Van; Froiio, Antonella; Paolesse, Roberto; Monti, Donato; Tagliatesta, Pietro; Boschi, Tristano; Prodi, Luca; Bolletta, Fabrizio; Zaccheroni, Nelsi

Book ID
125511765
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
105 KB
Volume
37
Category
Article
ISSN
0020-1669

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## Abstract As bioโ€inspired chemical model of the oxygenโ€evolving complex (OEC) in photosystem II, a new tyrosineโ€modified corrole ligand **3** and its highโ€valent copper and manganese complexes **3a** and **3b** were synthesized and characterized. The copper complexes **1a** and **2a** of corrole