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Synthesis, crystal structures, Mössbauer spectra, and redox properties of binuclear and tetranuclear iron-sulfur nitrosyl clusters

✍ Scribed by N. A. Sanina; I. I. Chuev; S. M. Aldoshin; N. S. Ovanesyan; V. V. Strelets; Yu. V. Geletii


Publisher
Springer
Year
2000
Tongue
English
Weight
685 KB
Volume
49
Category
Article
ISSN
1573-9171

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Bis(terdentate) Pyrazole/Pyridine Ligand
✍ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB 👁 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~