Synthesis, crystal structures and thermal decomposition kinetics of four new lanthanide complexes with 3,4-dimethylbenzoic acid and 1,10-phenanthroline
β Scribed by Hong-Mei Ye; Ning Ren; Jian-Jun Zhang; Shu-Jing Sun; Juan-Fen Wang
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 462 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1040-0400
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## Abstract The complex [Sm(__p__βMBA)~3~phen]~2~ (__p__βMBA, __p__βmethylbenzoate; phen, 1,10βphenanthroline) was prepared and characterized by elemental analysis, IR and UV spectra. The thermal decomposition process of [Sm(__p__β MBA)~3~phen]~2~ was studied under a static air atmosphere by TGβDTG
This paper presents three new lanthanide coordination polymers [Pr 2 (pim) Er, 3) prepared by the hydrothermal reaction. The structural details of complexes 1, 2 and 3 are reported. In complex 1, the Pr(III) ions are bridged by pim in three modes to form 2D layers. Adjacent layers are assembled by