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Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability

✍ Scribed by Andrey Yu. Rogachev; Andrey V. Mironov; Sergey I. Troyanov; Natalia P. Kuzmina; Alexander V. Nemukhin


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
353 KB
Volume
789
Category
Article
ISSN
0022-2860

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (