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Synthesis, Crystal Structures, and Optical Properties of Two New Layered Quaternary Tantalum Thiophosphates and the Thermal Conversion of Cs4Ta4P4S24 into Cs2Ta2P2S12.

โœ Scribed by Andreas Gutzmann; Christian Naether; Wolfgang Bensch


Publisher
John Wiley and Sons
Year
2004
Weight
62 KB
Volume
35
Category
Article
ISSN
0931-7597

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The new heteroleptic chromium complex [Ph 4 P][Cr(en)(S 5 ) 2 ] has been synthesised under mild solvothermal conditions by the reaction of chromium trichloride, sulfur, and tetraphenylphosphoniumbromide in a solution of ethylendiamine (en) in water. The crystal structure consists of isolated tetraph