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Synthesis, Crystal Structures, and Magnetic Properties of Three Novel Ferrocenecarboxylato-Bridged Lanthanide Dimers

✍ Scribed by Hou, Hongwei; Li, Gang; Li, Linke; Zhu, Yu; Meng, Xiangru; Fan, Yaoting

Book ID
120917789
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
285 KB
Volume
42
Category
Article
ISSN
0020-1669

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## Abstract Reactions of Mn(ClO~4~)~2~Β·6H~2~O with FcCO~2~Na [Fc = (Ξ·^5^‐C~5~H~4~)Fe(Ξ·^5^‐C~5~H~5~)] in methanol solution gave [Mn~3~(FcCO~2~)~6~(CH~3~OH)~4~]__~n~__ (1), and, in the presence of 4,4′‐bipyridine (4,4′‐bpy), [Mn~3~(FcCO~2~)~6~(H~2~O)~2~(4,4′‐bpy)]__~n~__ (2). Both complexes have the