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Synthesis, crystal structures and chemical bonding of RE 5− x Li x Ge 4 (RE = Nd, Sm and Gd; x ≃ 1) with the orthorhombic Gd 5 Si 4 type

✍ Scribed by Suen, Nian-Tzu; You, Tae-Soo; Bobev, Svilen


Book ID
119770937
Publisher
International Union of Crystallography
Year
2012
Tongue
English
Weight
575 KB
Volume
69
Category
Article
ISSN
0108-2701

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✍ Wolfgang Jeitschko; Dieter H Heumannskämper; Marietta S Schriewer-Pöttgen; Ute C 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 268 KB

Most of the title compounds were prepared by reaction of the rare-earth metaperrhenates Ln(ReO 4 ) 3 with the rare-earth metals in sealed silica tubes. Nd 4 Re 6 O 19 was obtained by reaction of the intermetallic compound NdRe 2 with the metaperrhenate Nd(ReO 4 ) 3 . The compounds Ln 2 ReO 5 crystal