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Synthesis, Crystal Structure from Single-Crystal and Powder X-ray Diffraction Data, and Thermal Behavior of Mixed Potassium Lanthanide Squarates: Thermal Transformations of Layered [Ln(H2O)6]K(H2C4O4)(C4O4)2 into Pillared LnK(C4O4)2 (Ln = Y, La, Gd, Er)

✍ Scribed by Mahé, Nathalie; Bataille, Thierry


Book ID
111902307
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
505 KB
Volume
43
Category
Article
ISSN
0020-1669

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Crystal Structure and Thermal Behavior o
✍ T. Bataille; M. Louër; J.-P. Auffrédic; D. Louër 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 611 KB

The crystal structure of La(H 2 O) 2 K(C 2 O 4 ) 2 ' H 2 O has been solved ab initio from powder di4raction data collected with conventional monochromatic X-rays. The symmetry is monoclinic, space group C2/m, cell dimensions a ‫؍‬ 22.033(1) A > , b ‫؍‬ 7.6003(5) A > , c ‫؍‬ 6.6418(4) A > , ‫؍‬ 103.8