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Synthesis, Crystal Structure, and Transistor Performance of Tetracene Derivatives

โœ Scribed by Moon, Hyunsik; Zeis, Roswitha; Borkent, Evert-Jan; Besnard, Celine; Lovinger, Andrew J.; Siegrist, Theo; Kloc, Christian; Bao, Zhenan

Book ID
111872678
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
99 KB
Volume
126
Category
Article
ISSN
0002-7863

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5,12-Diphenyl-6,11-bis(thien-2-yl)tetracene (1) was prepared by reduction of 5,12-diphenyl-6,11-bis(thien-2-yl)-6,11-tetracenediol (3) with NaBH 3 CN in the presence of weak Lewis acid ZnI 2 . A rearranged byproduct, 6,11-dihydro-5,12-diphenyl-6,6 0 -bis(thien-2-yl)-11, 11 0 -dihydrotetracene (5), w