Synthesis, crystal structure and thermal behavior of Rb(NTO) · H2O
✍ Scribed by Mancheng Hu; Shiyang Gao; Zhihong Liu; Jirong Song; Shuping Xia; Kaibei Yu
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 331 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1001-6538
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The crystal structure of synthetic Rb 2 [B 4 O 5 (OH) 4 ] ' 3.6H 2 O has been established from single-crystal X-ray di4raction data. It crystallizes in the orthorhombic space group Pbcn with a unit cell of dimensions a ؍ 11.276(5) A s , b ؍ 13.097(14) A s , c ؍ 16.751(5) A s ; V ؍ 2474(3) A
Single crystals of Pr(ClO 3 ) 3 ´2 H 2 O have been obtained from the reaction of Pr 2 (CO 3 ) 3 ´x H 2 O and HClO 3 . The crystal structure (orthorhombic, P2 1 2 1 2 1 , Z = 4, a = 576.03(7), b = 1236.7(2), c = 1314.0(2) pm) contains Pr 3+ ions coordinated by two H 2 O molecules and seven ClO 3 ± gr