✦ LIBER ✦

Synthesis, crystal structure and thermal behavior of a novel oxoborate SrBi2B4O10

✍ Scribed by M.G. Krzhizhanovskaya; R.S. Bubnova; A.V. Egorysheva; M.S. Kozin; V.D. Volodin; S.K. Filatov

Publisher: Elsevier Science
Year: 2009
Tongue: English
Weight: 677 KB
Volume: 182
Category: Article
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2009.02.011

No coin nor oath required. For personal study only.

✦ Synopsis

A new compound, SrBi 2 B 4 O 10 , has been grown by cooling a melt with the stoichiometric composition. It is triclinic, PÀ1, a ¼ 6.819(1), b ¼ 6.856(1), c ¼ 9.812(2) A ˚, a ¼ 96.09(1), b ¼ 109.11(1), g ¼ 101.94(1)1,

The crystal structure of the compound has been solved by direct methods and refined to R 1 ¼ 0.050 (wR 2 ¼ 0.128). The structure contains Bi-O pseudolayers build up from Bi-O chains involving oxocentred OBi 3 triangles. Sr atoms and [B 4 O 9 ] 6À isolated anions (4B:3D&:o2D&4D) are located between the Bi-O packages.

The thermal treatment as well as DSC experiment showed that the compound melts above 800 1C presumably according to the peritectic reaction: SrBi 2 B 4 O 10 2 SrB 2 O 4 +SrB 4 O 7 + Liquid. According to high-temperature X-ray powder diffraction study thermal expansion of SrBi 2 B 4 O 10 structure is anisotropic (a 11 ¼ 13, a 22 ¼ 9, a 33 ¼ 2, a V ¼ 24 Â 10 À6 1C À1 ).

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis, Crystal

ChemInform Abstract: Synthesis, Crystal Structure and Thermal Behavior of a Novel Oxoborate SrBi2B4O10.

✍ M. G. Krzhizhanovskaya; R. S. Bubnova; A. V. Egorysheva; M. S. Kozin; V. D. Volo 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 17 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Synthesis, Crystal Structure and Thermal

Synthesis, Crystal Structure and Thermal Behavior of Na4 [B10O16(OH)2]×4H2O.

✍ Zhi-Hong Liu; Lian-Qing Li; Ming-Zhen Wang 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB 👁 1 views

Synthesis and Crystal Structure of a Nov

Synthesis and Crystal Structure of a Novel Ternary Oxoborate, PbBiBO4.

✍ Xuean Chen; Jianlong Zuo; Xinan Chang; Yinghua Zhao; Hegui Zang; Weiqiang Xiao 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB 👁 2 views

Synthesis and crystal structure of a nov

Synthesis and crystal structure of a novel ternary oxoborate, PbBiBO4

✍ Xuean Chen; Jianlong Zuo; Xinan Chang; Yinghua Zhao; Hegui Zang; Weiqiang Xiao 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 259 KB

A novel ternary borate oxide, lead bismuth boron tetraoxide, PbBiBO 4 , has been prepared by solid-state reaction at temperature below 800 1C. The single-crystal X-ray structural analysis showed that PbBiBO 4 crystallizes in the monoclinic space group P2 1 /n with a ¼ 7:473ð1Þ Å, b ¼ 7:517ð1Þ Å, c ¼

Crystal structure and thermal behavior o

Crystal structure and thermal behavior of NaCs[B4O5(OH)4]·4H2O

✍ Jianguo Zhou; Fengying Zhao; Shuping Xia; Shiyang Gao 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 150 KB

ChemInform Abstract: K2[Te4O8(OH)10]: Sy

ChemInform Abstract: K2[Te4O8(OH)10]: Synthesis, Crystal Structure and Thermal Behavior.

✍ Yonglin An; Ahmed Mosbah; Annie Le Gal La Salle; Dominique Guyomard; Alain Verba 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v