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Synthesis, crystal structure and reaction of differentially ring-substituted titanocene dichlorides

✍ Scribed by Qian Yanlong; Li Guisheng; Chen Weichun; Li Bihua; Jin Xianglin


Publisher
Springer
Year
1990
Tongue
English
Weight
400 KB
Volume
15
Category
Article
ISSN
0340-4285

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Synthesis of 1-Methyl-3-aryl-substituted
✍ Yan-Long Qian; Xin-Rong Qin; Ji-Ling Huang; Albert Sun-Chi Chan; Shou-Shan Chen; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~·2THF, ZrCl~4~ and (CpTiCl~