Synthesis of 1-Methyl-3-aryl-substituted
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Yan-Long Qian; Xin-Rong Qin; Ji-Ling Huang; Albert Sun-Chi Chan; Shou-Shan Chen;
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Article
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2010
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John Wiley and Sons
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English
⚖ 292 KB
## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~·2THF, ZrCl~4~ and (CpTiCl~