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Synthesis, crystal structure and properties of SmBaCo2−xFexO5+δ

✍ Scribed by Volkova, N.E.; Gavrilova, L.Ya.; Cherepanov, V.A.; Aksenova, T.V.; Kolotygin, V.A.; Kharton, V.V.

Book ID: 120436543
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 690 KB
Volume: 204
Category: Article
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2013.06.001

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The room-temperature crystal structure of the brownmillerite SrCaMnGaO 5+d (d ¼ 0:035) has been refined from neutron powder diffraction data; space group Ima2, a ¼ 15:7817ð6Þ; b ¼ 5:4925ð2Þ, c ¼ 5:3196ð2Þ ( A. Mn and Ga occupy 99.0(2)% of the 6-and 4-coordinate sites, respectively. A combination of