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Synthesis, Crystal Structure and Properties of Calcium and Barium Hydroxyapatites Containing Copper Ions in Hexagonal Channels.

✍ Scribed by Andrey S. Karpov; Juergen Nuss; Martin Jansen; Pavel E. Kazin; Yury D. Tretyakov

Publisher
John Wiley and Sons
Year
2003
Weight
60 KB
Volume
34
Category
Article
ISSN
0931-7597

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(Β΅-OH)(bpy) 2 (H 2 O)](NO 3 )β€’2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]β€’2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.