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Synthesis, crystal structure and magnetic properties of a series of polymeric lanthanoid–copper complexes [Ln2Cu3{O(CH2−CO2)2}6]·nH2O (Ln=La, Nd,n=9; Ln=Er, n=6)

✍ Scribed by Jiang-Gao Mao; Jin-Shun Huang; Jian-Fang Ma; Jia-Zuan Ni


Book ID
110371585
Publisher
Springer
Year
1997
Tongue
English
Weight
305 KB
Volume
22
Category
Article
ISSN
0340-4285

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Preparation, Crystal Structures, and Pro
✍ Wolfgang Jeitschko; Dieter H Heumannskämper; Marietta S Schriewer-Pöttgen; Ute C 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 268 KB

Most of the title compounds were prepared by reaction of the rare-earth metaperrhenates Ln(ReO 4 ) 3 with the rare-earth metals in sealed silica tubes. Nd 4 Re 6 O 19 was obtained by reaction of the intermetallic compound NdRe 2 with the metaperrhenate Nd(ReO 4 ) 3 . The compounds Ln 2 ReO 5 crystal