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Synthesis, Crystal Structure, and Magnetic Properties of a One-Dimensional Polymeric Copper(II) Complex Containing an Unusual 1,1‘-Bicoordinated Oxalato Bridge

✍ Scribed by Castillo, Oscar; Luque, Antonio; Sertucha, Jon; Román, Pascual; Lloret, Francesc

Book ID
120224671
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
55 KB
Volume
39
Category
Article
ISSN
0020-1669

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## Abstract The synthesis, X‐ray crystal structure and magnetic properties of two oxalato‐bridged dinuclear Cu^II^ complexes, [L‐Cu(μ‐ox)Cu‐L](ClO~4~)~2~, where ox = oxalate and L = 1,4,7‐trimethyl‐1,4,7‐triazacyclononane (Me~3~tacn) or 1‐benzyl‐4,7‐dimethyl‐1,4,7‐triazacyclononane (BzMe~2~tacn) ar