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Synthesis, crystal structure and magnetic properties of a linear trinuclear copper(II) compound with chloride and 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole as bridging ligands

✍ Scribed by van Koningsbruggen, Petra J.; van Hal, Jaap W.; de Graaff, Rudolf A. G.; Haasnoot, Jaap G.; Reedijk, Jan


Book ID
118124230
Publisher
The Royal Society of Chemistry
Year
1993
Tongue
English
Weight
660 KB
Volume
14
Category
Article
ISSN
1472-7773

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First Complexes of a 4-Alkyl-3,5-di(2-py
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~