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Synthesis, Crystal Structure and Insecticidal Activity of the Optical Active Neonicotinoid Analogues

✍ Scribed by Sijia Xue; Hongfei Bu; Li Liu; Xiao Xu; Xubo Ma


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
582 KB
Volume
29
Category
Article
ISSN
0256-7660

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✦ Synopsis


Abstract

Eight novel neonicotinoid analogues 1‐(2‐tetrahydrofurfuryl)‐5‐substituted‐1,3,5‐hexahydrotriazine‐2‐N‐nitroimines 3a3h were synthesized, and their structures were characterized by ^1^H NMR, IR and elemental analysis. The stereostructure of 3a was determined by the single‐crystal X‐ray analysis, which exhibits a half‐chair conformation and dihedral angle is 49.70°. The preliminary bioassay tests showed that all the title compounds exhibited good insecticide activities against Nilaparvata legen (N. legen).


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