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Synthesis, crystal structure and herbicidal activity of mimics of intermediates of the KARI reaction

โœ Scribed by Bao-Lei Wang; Ronald G Duggleby; Zheng-Ming Li; Jian-Guo Wang; Yong-Hong Li; Su-Hua Wang; Hai-Bin Song


Book ID
105359609
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
122 KB
Volume
61
Category
Article
ISSN
1526-498X

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โœฆ Synopsis


Abstract

Two mimics of the intermediate in the reaction catalyzed by ketolโ€acid reductoisomerase (KARI) were synthesized. Their structures were established on the basis of elemental analyses, IR, ^1^H NMR and GC/mass detector. The crystal structure of compound 2 was found to be a substituted dioxane, formed by the condensation of two molecules. The two compounds showed some herbicidal activity on the basis of tests using rape root and barnyard grass growth inhibition. However, the herbicidal effect was weaker in greenhouse tests. Copyright ยฉ 2004 Society of Chemical Industry


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